The Remediation Pendulum: Revisiting Physical Remediation Using State‐of‐the‐Science Design Principles     

Suthan Suthersan  Denice Nelson  Shawn Burnell  John Horst 《Ground Water Monitoring & Remediation》2014,34(1):30-34

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Lithium, boron and chlorine as tracers for metasomatism in high-pressure metamorphic rocks: a case study from Syros (Greece)     

Horst R. Marschall  Rainer Altherr  Katalin Gméling  Zsolt Kasztovszky 《Mineralogy and Petrology》2009,95(3-4):291-302

High-pressure metamorphic (HPM) rocks (derived from igneous protoliths) and their metasomatised rinds from the island of Syros (Greece) were analysed for their B and Cl whole-rock abundances and their H₂O content by prompt-gamma neutron-activation analysis (PGNAA) and for their Li and Be whole-rock abundances by ICP-OES. In the HPM rocks, B?/Be and Cl?/Be ratios correlate with H₂O contents and appear to be controlled by extraction of B and Cl during dehydration and prograde metamorphism. In contrast, samples of the metasomatised rinds show no such correlation. B?/Be ratios in the rinds are solely governed by the presence or absence of tourmaline, and Cl?/Be ratios vary significantly, possibly related to fluid inclusions. Li/Be ratios do not correlate with H₂O contents in the HPM rocks, which may in part be explained by a conservative behaviour of Li during dehydration. However, Li abundances exceed the vast majority of published values for Li abundances in fresh, altered, or differentiated oceanic igneous rocks and presumably result from metasomatic enrichment of Li. High Li concentrations and highly elevated Li/Be ratios in most metasomatised samples demonstrate an enrichment of Li in the Syros HP mélange during fluid infiltration. This study suggests that B and Cl abundances of HPM meta-igneous rocks can be used to trace prograde dehydration, while Li concentrations seem to be more sensitive for retrograde metasomatic processes in such lithologies.  相似文献   

Mechanisms of metasomatic reactions     

Daniel E. Harlov  Horst R. Marschall 《Mineralogy and Petrology》2009,95(3-4):159-161

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Transfer functions simulating the coprecipitation of trace elements in unsaturated soils     

Veith Becker  Tanja Lager  Horst D. Schulz 《Environmental Geology》2009,58(7):1601-1609

Transfer functions describing the coprecipitation of various trace elements (TE; As, Cd, Co, Cu, Cr, Mo, Ni, Pb, Zn), precipitating with iron(oxihydr)oxides from an aqueous solution, were developed and implemented in the computer model ‘Seeper’. ‘Seeper’ was developed to predict the progression of the concentrations of inorganic pollutants in unsaturated soils underneath contaminated areas and to evaluate the prospective contamination of the groundwater. Transfer functions provide a straight and simple relation between the coprecipitation of TE and easy to obtain standard soil parameters, without excessive repercussions on the usability and computation time of the model. Laboratory experiments were conducted to quantify coprecipitation in solutions with pH values ranging from 5 to 12 and containing various iron and TE concentrations. For the examined TE, the transfer functions describe the coprecipitated fraction as a function of the pH value and the concentration ratio between precipitated iron and a TE. The transfer functions yielded a good prediction of cadmium, cobalt, copper, molybdenum, nickel, and zinc (R ² from 0.73 to 0.83). As for arsenic, chromium, and lead the correlation was not as good albeit a significant influence of precipitating iron on the mobility of these elements was observed and represented in the corresponding transfer functions.  相似文献   

Evaluation of remotely‐sensed DEMs and modification based on plausibility rules and initial sediment budgets of an artificially‐created catchment     

Anna Schneider  Horst H. Gerke  Thomas Maurer  Stefan Seifert  Rossen Nenov  Reinhard F. Hüttl 《地球表面变化过程与地形》2012,37(7):708-725

To quantify landscape change resulting from processes of erosion and deposition and to establish spatially distributed sediment budgets, ‘models of change’ can be established from a time series of digital elevation models (DEMs). However, resolution effects and measurement errors in DEMs may propagate to these models. This study aimed to evaluate and to modify remotely‐sensed DEMs for an improved quantification of initial sediment mass changes in an artificially‐created catchment. DEMs were constructed from photogrammetry‐based, airborne (ALS) and ground‐based laser scanning (TLS) data. Regions of differing morphological characteristics and vegetation cover were delineated. Three‐dimensional (3D) models of volume change were established and mass change was derived from these models. DEMs were modified region‐by‐region for rill, interrill and alluvial areas, based on logical and hydro‐geomorphological principles. Additional DEMs were constructed by combining multi‐source, modified data. Models were evaluated by comparison with d‐GPS reference data and by considering sediment budget plausibility. Comprehensive evaluation showed that DEM usability depends on a relation between the technique used to obtain elevation data, surface morphology and vegetation cover characteristics. Photogrammetry‐based DEMs were suited to quantification of change in interrill areas but strongly underestimated surface lowering in erosion rills. TLS DEMs were best suited to rill areas, while ALS DEMs performed best in vegetation‐covered alluvial areas. Agreement with reference data and budget plausibility were improved by modifications to photogrammetry‐ and TLS‐based DEMs. Results suggest that artefacts in DEMs can be reduced and hydro‐geomorphic surface structures can be better represented by applying region‐specific modifications. Photogrammetry‐based DEMs can be improved by combining higher and lower resolution data in defined structural units and applying modifications based on principles given by characteristic hydro‐geomorphic evolution. Results of the critical comparative evaluation of remotely‐sensed elevation data can help to better interpret DEM‐based quantifications of earth‐surface processes. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Ground-motion scenarios on Mt. Etna inferred from empirical relations and synthetic simulations     

Horst Langer  Giuseppina Tusa  Luciano Scarfì  Raffaele Azzaro 《Bulletin of Earthquake Engineering》2016,14(7):1917-1943

Ground motion scenarios for Mt. Etna are created using synthetic simulations with the program EXSIM. A large data set of weak motion records is exploited to identify important input parameters which govern the modeling of wave propagation effects, such as Q-values, high frequency cut-off and geometrical spreading. These parameters are used in the simulation of ground motion for earthquakes causing severe damage in the area. Two seismotectonic regimes are distinguished. Volcano-tectonic events, though being of limited magnitude (M_max ca. 5), cause strong ground shaking for their shallow foci. Being rather frequent, these events represent a considerable threat to cities and villages on the flanks of the volcano. A second regime is related to earthquakes with foci in the crust, at depths of 10–30 km, and magnitudes ranging from 6 to 7. In our synthetic scenarios, we chose two examples of volcano-tectonic events, i.e. the October 29, 2002, Bongiardo event (I = VIII) and the May 8, 1914, Linera earthquake (I = IX–X). A further scenario regards the February 20, 1818 event, considered representative for stronger earthquakes with foci in the crust. We were able to reproduce the essential features of the macroseismic field, in particular accounting for the possibility of strong site effects. We learned that stress drop estimated for weak motion events is probably too low to explain the intensity of ground motion during stronger earthquakes. This corresponds to findings reported in the literature claiming an increase of stress drop with earthquake size.  相似文献   

Interaction of bentonite colloids with Cs, Eu, Th and U in presence of humic acid: A flow field-flow fractionation study   总被引：2，自引：0，他引：2  

Muriel Bouby  Horst Geckeis  Silvia Mihai  Thorsten Schäfer 《Geochimica et cosmochimica acta》2011,75(13):3866-3880

The interaction of Cs(I), Eu(III), Th(IV) and U(VI) with montmorillonite colloids was investigated in natural Grimsel Test Site groundwater over a 3 years period. The asymmetric flow field-flow fractionation combined with various detectors was applied to study size variations of colloids and to monitor colloid association of trace metals. The colloids suspended directly in the low ionic strength (I), slightly alkaline granitic groundwater (I = 10⁻³ mol/L, pH 9.6) showed a gradual agglomeration with a size distribution shift from initially 10-200 nm to 50-400 nm within over 3 years. The Ca²⁺ concentration of 2.1 × 10⁻⁴ mol/L in the ground water is believed to be responsible for the slow agglomeration due to Ca²⁺ ion exchange against Li⁺ and Na⁺ at the permanently charged basal clay planes. Furthermore, the Ca²⁺ concentration lies close to the critical coagulation concentration (CCC) of 10⁻³ mol L⁻¹ for clay colloids. Slow destabilization may delimit clay colloid migration in this specific groundwater over long time scales. Eu(III) and Th(IV) are found predominantly bound to clay colloids, while U(VI) prevails as the UO₂(OH)₃⁻ complex and Cs(I) remains mainly as aquo ion under our experimental conditions. Speciation calculations qualitatively represent the experimental data. A focus was set on the reversibility of metal ion-colloid binding. Addition of humic acid as a competing ligand induces rapid metal ion dissociation from clay colloids in the case of Eu(III) even after previous aging for about 3 years. Interestingly only partial dissociation occurs in the case of Th(IV). Experiments and calculations prove that the humate complexes dominate the speciation of all metal ions under given conditions. The partial irreversibility of clay bound Th(IV) is presently not understood but might play an important role for the colloid-mediated transport of polyvalent actinides over wide distances in natural groundwater.  相似文献   

Increasing levels and biomagnification of persistent organic pollutants (POPs) in Antarctic biota   总被引：3，自引：0，他引：3  

Goerke H  Weber K  Bornemann H  Ramdohr S  Plötz J 《Marine pollution bulletin》2004,48(3-4):295-302

Representatives of the Antarctic food web (krill, cephalopod, fish, penguin, seal) of the area around Elephant Island and from the Weddell Sea were analysed for the most recalcitrant organochlorine compounds. Due to sorption of the compounds to sinking particles and accumulation in sediments, two benthic fish species (Gobionotothen gibberifrons, Chaenocephalus aceratus) feeding on benthos invertebrates and fish reflected significantly increasing concentrations within a decade (1987-1996), while a benthopelagic species (Champsocephalus gunnari) feeding on krill did not. In the pelagic food chain, lipid normalised concentrations of all compounds increased from Antarctic krill to fish proving that biomagnification of highly lipophilic pollutants (log octanol-water partition coefficient>5) occurs in water-breathing animals. As top predators Weddell and southern elephant seals (Leptonychotes weddellii, Mirounga leonina) biomagnified the persistent organic pollutants relative to krill 30-160 fold with the exception of hexachlorobenzene, the levels of which were lower than in fish indicating its intense specific elimination.  相似文献   

区域农业用地营养盐剩余量的长期变化研究   总被引：5，自引：4，他引：1  

许朋柱  秦伯强  香宝  单正军  BEHRENDT Horst  黄文钰 《地理科学》2006,26(6):668-673

根据太湖南部长兴县农业统计资料,对该地区1949~2002年农业用地上N、P的剩余量作出评估。评估结果认为,1949~2002年期间,单位农业用地面积的N、P剩余量具有显著地增加趋势。20世纪50及60年代期间,N的剩余量增加缓慢,自70年代中期以后增加迅速。1996年达到历史最大值。1996年后,N剩余量呈现减少趋势。60年代初期以前,P处于亏损状态。1975~1980年期间,P剩余量呈现缓慢增长趋势,其后出现回落,自80年代中期以后出现迅速增加趋势。1992~1998年期间,P剩余量维持在35~45 kg/(hm²·a)之间的高水平变化,自1999年以后出现显著回落。  相似文献   

Quiet-time periods observed by EPHIN/SOHO during the minimum of the 22nd solar cycle     

Gómez-Herrero  Raúl  RodrÍguez-FrÍas  M. Dolores  del Peral  Luis  Sequeiros  Juan  Müller-Mellin  Reinhold  Kunow  Horst  Sierks  Holger 《Solar physics》2000,194(2):405-413

An analysis of the hydrogen and helium isotopic composition from EPHIN data, during the quiet-time period from January 1 to June 1, 1996, is presented. An isotopic discrimination and background rejection have been applied and relationships between the abundances of ²H/¹H, ³He/⁴He, and ⁴He/¹H have been calculated. The energy spectra in the 4–50 MeV nucl^–1 range have been obtained and the contribution of the different spectral components have been analysed in this energy range. We conclude that the main contribution to the ⁴He spectrum is of anomalous origin, while the proton and ³He spectra have contributions mainly from particles of solar origin at low energies and from the galactic cosmic radiation modulated by the heliosphere at high energies. The deuterium spectrum is mainly of galactic origin.  相似文献